A few things to do after a Fresh kali install - Beginner

Update and upgrade if you have not already
apt-get update
apt-get upgrade
apt-get dist-upgrade

Change to the official repositories!!!!!! ## Regular repositories
deb http://http.kali.org/kali kali main non-free contrib
deb http://security.kali.org/kali-security kali/updates main contrib non-free
## Source repositories
deb-src http://http.kali.org/kali kali main non-free contrib
deb-src http://security.kali.org/kali-security kali/updates main contrib non-free

open and install the i386 version of wine
Wine will have instructions but if you have trouble with the A64 version then just reinstall off there site.

Download and update your version of PHP so that you can run things like Metasploit Pro grabber!
If you are someone who uses metasploit then download the metasploit Pro Trial grabber here: https://github.com/kulisu/metasploit-pro-trial-grabber THIS IS NOT PIRATING as it only speeds up the process of a free trial grab by using pre made emails etc.

The following are more of an option than a need.

Assuming you followed my advice and installed wine, go to www.nirsoft.net and install some of the following tools:

Fast Resolver - Makes resolving large amounts of links a piece of cake, also has resumable sessions.
Web_Grabber - (the newer version may require wine) - This is a tool that once you gain access to something, allows you to snag saved passwords for most top browsers (Chrome, IE, Opera, Firefox

This is just a start, leave a comment/pm if any of you would like more