[JohnTravolta3242]

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[Wotara]

Try making the animation in AE, then export in PNG sequence, and continue to export in PS.

Here is an example I put together.
http //imageshack.com/a/img537/710/o2uP6H.gif

There is only so far you can go in terms of quality.

[pissedaf]

if you are using Photoshop, you cannot.
if you are using an actual 3D program and applying your avatar as a texture then you can simply add a smooth modifier on it